Hebron was:

Associated with the patriarchs
Genesis 13:18 - Then Abram removed [his] tent, and came and dwelt in the plain of Mamre, which [is] in Hebron, and built there an altar unto the LORD.
Genesis 23:2 - And Sarah died in Kirjatharba; the same [is] Hebron in the land of Canaan: and Abraham came to mourn for Sarah, and to weep for her.
Genesis 35:27 - And Jacob came unto Isaac his father unto Mamre, unto the city of Arbah, which [is] Hebron, where Abraham and Isaac sojourned.

Visited by Israelite spies
Numbers 13:22 - And they ascended by the south, and came unto Hebron; where Ahiman, Sheshai, and Talmai, the children of Anak, [were]. (Now Hebron was built seven years before Zoan in Egypt.)

Taken by Joshua
Joshua 10:36 - And Joshua went up from Eglon, and all Israel with him, unto Hebron; and they fought against it:
Joshua 14:13 - And Joshua blessed him, and gave unto Caleb the son of Jephunneh Hebron for an inheritance.
Joshua 14:14 - Hebron therefore became the inheritance of Caleb the son of Jephunneh the Kenezite unto this day, because that he wholly followed the LORD God of Israel.
Joshua 14:15 - And the name of Hebron before [was] Kirjatharba; [which Arba was] a great man among the Anakims. And the land had rest from war.

Located in the hill country of Judah
Joshua 15:54 - And Humtah, and Kirjatharba, which [is] Hebron, and Zior; nine cities with their villages:

A city of refuge
Joshua 20:7 - And they appointed Kedesh in Galilee in mount Naphtali, and Shechem in mount Ephraim, and Kirjatharba, which [is] Hebron, in the mountain of Judah.
Judges 1:10 - And Judah went against the Canaanites that dwelt in Hebron: (now the name of Hebron before [was] Kirjatharba:) and they slew Sheshai, and Ahiman, and Talmai.

David's capital
2 Samuel 2:1 - And it came to pass after this, that David enquired of the LORD, saying, Shall I go up into any of the cities of Judah? And the LORD said unto him, Go up. And David said, Whither shall I go up? And he said, Unto Hebron.
2 Samuel 2:2 - So David went up thither, and his two wives also, Ahinoam the Jezreelitess, and Abigail Nabal's wife the Carmelite. 
2 Samuel 2:3 - And his men that [were] with him did David bring up, every man with his household: and they dwelt in the cities of Hebron.
2 Samuel 2:11 - And the time that David was king in Hebron over the house of Judah was seven years and six months
2 Samuel 5:5 - In Hebron he reigned over Judah seven years and six months: and in Jerusalem he reigned thirty and three years over all Israel and Judah.

Where Absalom reigned
2 Samuel 15:10 - But Absalom sent spies throughout all the tribes of Israel, saying, As soon as ye hear the sound of the trumpet, then ye shall say, Absalom reigneth in Hebron.

Fortified
2 Chronicles 11:10 - And Zorah, and Aijalon, and Hebron, which [are] in Judah and in Benjamin fenced cities.
 

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Hebron in Bible Cities
More about Ancient Hebron

More About Ancient Hebron

Hebron Scriptures

1 Chronicles 12:38 - All these men of war, that could keep rank, came with a perfect heart to Hebron, to make David king over all Israel: and all the rest also of Israel [were] of one heart to make David king. 

2 Samuel 4:8 - And they brought the head of Ishbosheth unto David to Hebron, and said to the king, Behold the head of Ishbosheth the son of Saul thine enemy, which sought thy life; and the LORD hath avenged my lord the king this day of Saul, and of his seed. 

2 Samuel 3:19 - And Abner also spake in the ears of Benjamin: and Abner went also to speak in the ears of David in Hebron all that seemed good to Israel, and that seemed good to the whole house of Benjamin. 

1 Chronicles 29:27 - And the time that he reigned over Israel [was] forty years; seven years reigned he in Hebron, and thirty and three [years] reigned he in Jerusalem. 

2 Samuel 5:5 - In Hebron he reigned over Judah seven years and six months: and in Jerusalem he reigned thirty and three years over all Israel and Judah. 

1 Kings 2:11 - And the days that David reigned over Israel [were] forty years: seven years reigned he in Hebron, and thirty and three years reigned he in Jerusalem. 

Joshua 10:39 - And he took it, and the king thereof, and all the cities thereof; and they smote them with the edge of the sword, and utterly destroyed all the souls that [were] therein; he left none remaining: as he had done to Hebron, so he did to Debir, and to the king thereof; as he had done also to Libnah, and to her king. 

2 Samuel 3:20 - So Abner came to David to Hebron, and twenty men with him. And David made Abner and the men that [were] with him a feast. 

Joshua 11:21 - And at that time came Joshua, and cut off the Anakims from the mountains, from Hebron, from Debir, from Anab, and from all the mountains of Judah, and from all the mountains of Israel: Joshua destroyed them utterly with their cities. 

Joshua 10:23 - And they did so, and brought forth those five kings unto him out of the cave, the king of Jerusalem, the king ofHebron, the king of Jarmuth, the king of Lachish, [and] the king of Eglon. 

2 Samuel 2:1 - And it came to pass after this, that David enquired of the LORD, saying, Shall I go up into any of the cities of Judah? And the LORD said unto him, Go up. And David said, Whither shall I go up? And he said, Unto Hebron. 

1 Chronicles 3:4 - [These] six were born unto him in Hebron; and there he reigned seven years and six months: and in Jerusalem he reigned thirty and three years. 

Joshua 10:5 - Therefore the five kings of the Amorites, the king of Jerusalem, the king of Hebron, the king of Jarmuth, the king of Lachish, the king of Eglon, gathered themselves together, and went up, they and all their hosts, and encamped before Gibeon, and made war against it. 

Joshua 10:3 - Wherefore Adonizedek king of Jerusalem sent unto Hoham king of Hebron, and unto Piram king of Jarmuth, and unto Japhia king of Lachish, and unto Debir king of Eglon, saying, 

Joshua 12:10 - The king of Jerusalem, one; the king of Hebron, one; 

2 Samuel 3:32 - And they buried Abner in Hebron: and the king lifted up his voice, and wept at the grave of Abner; and all the people wept. 

Exodus 6:18 - And the sons of Kohath; Amram, and Izhar, and Hebron, and Uzziel: and the years of the life of Kohath [were] an hundred thirty and three years. 

1 Chronicles 2:42 - Now the sons of Caleb the brother of Jerahmeel [were], Mesha his firstborn, which was the father of Ziph; and the sons of Mareshah the father of Hebron. 

Joshua 15:13 - And unto Caleb the son of Jephunneh he gave a part among the children of Judah, according to the commandment of the LORD to Joshua, [even] the city of Arba the father of Anak, which [city is] Hebron. 

Joshua 21:11 - And they gave them the city of Arba the father of Anak, which [city is] Hebron, in the hill [country] of Judah, with the suburbs thereof round about it. 

Judges 16:3 - And Samson lay till midnight, and arose at midnight, and took the doors of the gate of the city, and the two posts, and went away with them, bar and all, and put [them] upon his shoulders, and carried them up to the top of an hill that [is] before Hebron. 

2 Samuel 3:22 - And, behold, the servants of David and Joab came from [pursuing] a troop, and brought in a great spoil with them: but Abner [was] not with David in Hebron; for he had sent him away, and he was gone in peace. 

1 Chronicles 6:57 - And to the sons of Aaron they gave the cities of Judah, [namely], Hebron, [the city] of refuge, and Libnah with her suburbs, and Jattir, and Eshtemoa, with their suburbs, 

Joshua 20:7 - And they appointed Kedesh in Galilee in mount Naphtali, and Shechem in mount Ephraim, and Kirjatharba, which [is] Hebron, in the mountain of Judah. 

Joshua 21:13 - Thus they gave to the children of Aaron the priest Hebron with her suburbs, [to be] a city of refuge for the slayer; and Libnah with her suburbs, 

Genesis 23:2 - And Sarah died in Kirjatharba; the same [is] Hebron in the land of Canaan: and Abraham came to mourn for Sarah, and to weep for her. 

Genesis 35:27 - And Jacob came unto Isaac his father unto Mamre, unto the city of Arbah, which [is] Hebron, where Abraham and Isaac sojourned. 

2 Samuel 15:10 - But Absalom sent spies throughout all the tribes of Israel, saying, As soon as ye hear the sound of the trumpet, then ye shall say, Absalom reigneth in Hebron. 

2 Samuel 3:5 - And the sixth, Ithream, by Eglah David's wife. These were born to David in Hebron. 

2 Samuel 5:13 - And David took [him] more concubines and wives out of Jerusalem, after he was come from Hebron: and there were yet sons and daughters born to David.    

Hebron (alliance). A city of Judah, Jos 15:54 situated among the mountains, Jos 20:7 20 Roman miles south of Jerusalem, and the same distance north of Beersheba. Hebron is one of the most ancient cities in the world still existing; and in this respect it is the rival of Damascus. It was a well-known town when Abraham entered Canaan, 3800 years ago. Ge 13:18 Its original name was Kirjath-arba, Jud 1:10 "the city of Arba;" so called from Arba the father of Anak. Jos 15:13,14; 21:13 Sarah died at Hebron; and Abraham then bought from Ephron the Hittite the field and cave of Machpelah, to serve as a family tomb Ge 23:2-20 The cave is still there, and the massive walls of the Haram or mosque, within which it lies, form the most remarkable object in the whole city. Abraham is called by Mohammedans el-Khulil, "the Friend," i.e. of God, and this is the modern name of Hebron. Hebron now contains about 5000 inhabitants, of whom some fifty families are Jews. It is picturesquely situated in a narrow valley, surrounded by rocky hills. The valley runs from north to south; and the main quarter of the town, surmounted by the lofty walls of the venerable Haram, lies partly on the eastern slope. Ge 37:14 comp. Gene 23:19 About a mile from the town, up the valley, is one of the largest oak trees in Israel. This, say some, is the very tree beneath which Abraham pitched his tent, and it still bears the name of the patriarch. 3. One of the towns in the territory of Asher, Jos 19:28 probably Ebdon or Abdom. - Smith
https://free-bible.com/smiths/H/Hebron/